Battery research focuses on balancing three competing factors:
performance, lifetime, and safety. Typically, you have to sacrifice one
of these factors to get gains in the other two. But for applications
like
electric vehicles, we'd really like to see all three improved.
In an investigation recently published in
Nature Energy,
scientists demonstrated the ability to use a magnetic field to align
graphite flakes within electrodes as they're manufactured. The alignment
gives
lithium ion a clearer path to transit the
battery, leading to improved performance.
The electrodes of
Lithium-ion batteries are often composed of graphite, which balances attributes such as a high energy density with non-toxicity,
safety, and
low cost.
Graphite, composed of stacked sheets of carbon atoms, is often
incorporated into these electrodes in the form of flake-like particles.
While graphite has many advantages, it has a downside: it limits the movement of
lithium ions, which is a fundamental part of charging and discharging. The
lithium ions are
only able to move within the planes between stacked graphene sheets and
often have to navigate a highly torturous path as they move around
during charge and discharge. This slow movement through the electrodes
remains a critical challenge in the development of
batteries with improved
performance.
The authors of the new paper reasoned that it should be possible to
align the graphite flakes so that they provide a more linear path for
ions to move within the battery. To accomplish this, they decided to use
magnetic fields. There was just one problem: graphite doesn't respond
to magnetic fields.
To work around this, the scientists coated the flakes with
superparamagnetic iron oxide nanoparticles. The coated graphite flakes
were then suspended in ethanol. They homogenized the suspension and
added a small amount of a chemical binder (2 percent by
weight poly (vinyl pyrrolidone) that helped ease the alignment process. A
relatively dilute suspension was needed to give the flakes enough room
to move during alignment.
During fabrication of the electrodes, the graphite particles were
oriented using a rotating magnetic field aligned perpendicular to the
part of the battery that would exchange charges with the graphite
(called a current collector). The scientists found that a magnetic field
as low as 100 mT was capable of aligning the flakes. For
comparison, this magnetic strength is larger than the average fridge
magnet (1 mT), but significantly smaller than an MRI magnet (1.5 T). As a
control, they also prepared reference electrodes in the absence of a
magnetic field.
After fabrication, the team evaluated the alignment of the graphite
flakes deposited under both conditions. Visual analysis revealed a
clear orientation of flakes in electrodes fabricated under the influence
of the magnetic field. The flakes were tilted at an angle of 60 degrees
above the plane of the current collector. By contrast, the graphite
flakes in the reference electrodes fell mostly parallel to the current
collector.
Next, the scientists carried out a series of experiments to evaluate the change in the path the
lithium ions needed
to navigate. Overall, they saw that the magnetic field decreased the
tortuosity of the paths through the electrode by a factor of 4 compared
to the reference electrodes.
Finally, they evaluated how this impacted the battery performance
by testing the electrode in a half-cell configuration (meaning they
didn't build a full battery). At practical charging rates, alignment of
the graphite flakes increased the
lithium storage capacity of the
electrode by a factor of between 1.6 and 3.
This investigation demonstrates that chemistry isn’t the only
important factor at play in battery design—optimization of the electrode
architecture can help boost battery performance as well. Future studies
will need to determine the scalability of this technique.
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